Qiji Chemical
Products

1 Bromopentane

Qiji Chemical

Specifications

HS Code

686455

Name 1 - Bromopentane
Molecular Formula C5H11Br
Molar Mass 151.045 g/mol
Appearance Colorless liquid
Odor Characteristic odor
Density 1.218 g/cm³ at 20 °C
Boiling Point 129 - 130 °C
Melting Point -95 °C
Solubility In Water Insoluble
Solubility In Organic Solvents Soluble in many organic solvents like ethanol, ether
Flash Point 31 °C
Vapor Pressure 1.95 kPa at 25 °C
Refractive Index 1.4428 at 20 °C
Packing & Storage
Packing 1 - Bromopentane packaged in 500 - mL glass bottles, each containing 500 mL quantity.
Storage 1 - Bromopentane should be stored in a cool, well - ventilated area, away from heat sources and open flames due to its flammability. It should be kept in a tightly - sealed container to prevent vapor leakage. Store it separately from oxidizing agents and incompatible substances. Use appropriate secondary containment to prevent spills from spreading.
Shipping 1 - Bromopentane is shipped in well - sealed, corrosion - resistant containers. It's classified as a hazardous chemical, so strict regulations govern its transport to ensure safety from potential flammability and toxicity risks during transit.
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General Information
Frequently Asked Questions
1 - What are the main physical properties of Bromopentane?
1-Bromopentane is an organic compound. Its main physical properties are as follows:
Viewed at room temperature, it is a colorless to light yellow liquid, clear and transparent, and has no impurities visible to the naked eye. Smell it, it has a special odor, although not strong and pungent, but it is unique and different from common hydrocarbon odors.
In terms of its density, it is heavier than water. If it is placed in the same container as water, 1-bromopentane will sink to the bottom and be stratified clearly. Its boiling point is in a certain range, about 129-130 ° C. At this temperature, 1-bromopentane changes from liquid to gas.
Solubility is also an important property. 1-bromopentane is insoluble in water because it is a non-polar molecule with a large difference in polarity from water molecules. According to the principle of "similar miscibility", the two are difficult to miscible. However, it is soluble in a variety of organic solvents, such as ethanol and ether. In organic synthesis experiments, such organic solvents are often used to dissolve 1-bromopentane to promote the reaction.
In addition, 1-bromopentane has a specific refractive index, which can be used for identification and purity analysis. In the field of organic chemistry, by measuring its refractive index, it can assist in judging the purity of the sample and whether it is the target product.
1 - What are the common uses of Bromopentane?
The common preparation methods of 1-bromopentane are as follows:
One is the reaction of pentanol with hydrobromic acid. This is a classic preparation method. The process is: make pentanol and hydrobromic acid co-heat, the hydroxyl group of pentanol will be replaced by bromine atoms, and then 1-bromopentane will be generated. The reaction principle is that the bromine ion in the hydrobromic acid nucleophilically attacks the carbon atom connected to the hydroxyl group in the pentanol, and the hydroxyl group leaves in the form of water to achieve the substitution reaction. During the specific operation, an appropriate amount of pentanol needs to be placed in the reaction vessel, slowly add hydrobromic acid, and heat and stir at the same time to promote the reaction to proceed fully. After the reaction is completed, the product is separated and purified by distillation and other means.
The second is to use pentane In this reaction, pentane and bromine undergo free radical substitution reaction under the action of light or initiator. Under the influence of light or initiator, bromine molecules are homogenized to form bromine radicals. Bromine radicals capture a hydrogen atom in the pentane molecule to form pentyl radicals. The pentyl radical reacts with bromine molecules to generate 1-bromopentane. This reaction produces a variety of bromogenic products. 1-bromopentane is not the only product, but also 2-bromopentane and other by-products. Therefore, after the reaction is completed, fine separation methods such as fractionation are required to obtain pure 1-bromopentane.
The third is prepared by the addition reaction of 1-pentene and hydrogen bromide. The carbon-carbon double bond of 1-pentene has high reactivity and can be added to hydrogen bromide. Following the Markov rule, hydrogen atoms will be added to the double-bonded carbon atoms with more hydrogen, and bromine atoms will be added to the double-bonded carbon atoms with less hydrogen, mainly producing 1-bromopentane. During operation, 1-pentene is introduced into the hydrogen bromide gas, or 1-pentene is reacted with the hydrogen bromide solution in a suitable solvent. After the reaction is completed, pure 1-bromopentane can be obtained through washing, drying, distillation and other steps.
1 - What are the synthesis methods of Bromopentane?
The synthesis methods of 1-bromopentane generally include the following.
First, pentanol is reacted with hydrobromic acid. This is a common method. When pentanol encounters hydrobromic acid, the hydroxyl group is replaced by a bromine atom, and then 1-bromopentane is obtained. The reaction requires a suitable temperature and catalyst to make the reaction smooth. Usually, sulfuric acid can be used as a catalyst to accelerate the reaction. During the reaction, the hydroxyl group in pentanol is nucleophilic, the bromine ion in hydrobromic acid nucleophilically attacks the carbon atom connected to the hydroxyl group, and the hydroxyl group leaves in the form of water, eventually forming 1-bromopentane. < Br >
Second, pentane is used as raw material and prepared by bromination reaction. However, pentane is brominated, and the obtained products are complex. Due to the different hydrogen atom activities at different positions of pentane, the substitution of bromine atoms is different. 1-bromopentane is only one of the products. To obtain high-purity 1-bromopentane, the reaction conditions, such as light intensity, bromine dosage, reaction temperature, etc. need to be finely adjusted to increase the yield of 1-bromopentane.
Third, the addition of 1-pentene to hydrogen bromide. This reaction follows the Markov rule. When the double bond of 1-pentene meets hydrogen bromide, the hydrogen atom is added to the double bond carbon atom containing more hydrogen, and the bromine atom is added to the double bond carbon atom containing less hydrogen, resulting in 1-bromopentane. This reaction condition is relatively mild and the yield is quite high. It is often a good method for synthesizing 1-bromopentane. However, the influence of peroxides should be paid attention to in the reaction. If there are peroxides, the reaction orientation may be different from the Markov rule, resulting in impure products.
1 - What do I need to pay attention to when storing and transporting Bromopentane?
1-Bromopentane is an organic compound, and many aspects must be paid attention to when storing and transporting it.
Let's talk about storage first. Because of its certain volatility and flammability, it should be stored in a cool and well-ventilated place, away from fire and heat sources, to prevent it from evaporating and forming flammable gases, which can cause fire or even explosion in case of open flame. It needs to be packed in a sealed container to avoid excessive contact with air. First, to prevent volatile loss, and second, to avoid it from reacting with certain components in the air. And it should be stored separately from oxidants, acids, etc., because 1-bromopentane may react chemically with these substances, resulting in deterioration or danger.
Let's talk about transportation. Transport vehicles must be equipped with fire and explosion-proof devices to deal with potential fire hazards that may occur during transportation. Transport personnel must undergo professional training and be familiar with the characteristics of 1-bromopentane and emergency treatment methods. When handling, they should be handled lightly to prevent damage to packaging containers and leakage of 1-bromopentane. In the event of a leak, personnel from the contaminated area of the leak should be quickly evacuated to a safe area and quarantined to strictly restrict access. Emergency personnel should wear self-contained positive pressure breathing apparatus and anti-toxic clothing to cut off the source of leakage as much as possible. When a small amount of leakage occurs, it can be absorbed by sand, vermiculite, or other inert materials. When a large amount of leakage occurs, a dike or pit should be built for containment, covered with foam, to reduce steam hazards, and transferred to a tanker or dedicated collector with an explosion-proof pump for recycling or transportation to a waste treatment site for disposal.
1 - What are the effects of Bromopentane on the environment and the human body?
1 + -Bromopentane is also an organic compound. Its impact on the environment and the human body cannot be ignored.
In terms of the environment, if 1 + -bromopentane is released in the atmosphere, it will gradually dissolve through photochemical reaction. In water bodies, it can volatilize and escape into the atmosphere, or be degraded by microorganisms. In soil, it can be adsorbed by soil particles, and some can be decomposed by microbial action. However, if this compound persists in the environment in large quantities, it may cause ecological imbalance and affect the growth and reproduction of organisms.
As for the impact on the human body, 1 + -bromopentane is irritating. If inhaled, it can cause respiratory discomfort, such as coughing, asthma, and even damage lung function. Skin contact with it, or redness, swelling, itching, burning. If not carefully entered the eye, it will cause severe pain and damage to the eye tissue. If eaten by mistake, it will cause gastrointestinal discomfort, such as nausea, vomiting, abdominal pain, etc. Long-term or repeated exposure may damage the nervous system, liver and kidneys, and cause chronic health problems.
Therefore, the use, storage and disposal of 1 + -bromopentane should be done with caution to reduce its harm to the environment and human body.