Qiji Chemical
Products

Allyl Bromide

Qiji Chemical

Specifications

HS Code

681124

Name Allyl Bromide
Chemical Formula C3H5Br
Molar Mass 120.98 g/mol
Appearance Colorless to pale - yellow liquid
Odor Pungent
Density 1.40 g/cm³
Boiling Point 71 - 73 °C
Melting Point -119 °C
Solubility In Water Slightly soluble
Solubility In Organic Solvents Soluble in many organic solvents like ethanol, ether
Flash Point -2 °C
Vapor Pressure 13.3 kPa (20 °C)
Packing & Storage
Packing Allyl Bromide in a 500 - mL glass bottle, tightly sealed for safe storage.
Storage Allyl bromide should be stored in a cool, well - ventilated area, away from heat, sparks, and open flames due to its flammability. Keep it in a tightly - sealed container to prevent vapor leakage. Store it separately from oxidizing agents, bases, and metals to avoid potentially hazardous reactions. Ensure storage areas comply with safety regulations for handling toxic and reactive chemicals.
Shipping Allyl bromide is a hazardous chemical. It must be shipped in accordance with strict regulations. Use appropriate packaging to prevent leakage, and label containers clearly. Ship via carriers approved for hazardous materials.
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General Information
Frequently Asked Questions
What are the main uses of Allyl Bromide?
Allyl bromide (Allyl Bromide) is also an important part of the chemical process. Its use is very important in the field of synthesis, and it is an important raw material for molecular production.
First, allyl bromide is often used to introduce allyl functionalities. Allyl functionalities are active, and can be multiplexed and reversed, such as nuclear substitution. In the synthetic pathway, allyl bromide is used to connect allyl to the target molecule conveniently, and to synthesize specific compounds.
Second, in the synthesis of compounds, allyl bromide also plays a role. Molecules often require the introduction of specific functions to improve the activity, solubility, and other properties of the compound. The introduction of allyl may modify the interaction of the compound and improve the efficiency.
Furthermore, in the field of materials, allyl bromide can be used in the synthesis of polymers. With allyl bromide or copolymerization, polymeric materials with special properties can be obtained. This material may have good mechanical properties and qualitative properties, etc., and has great application prospects in fields such as aerospace and electronics.
In addition, allyl bromide is also useful in the synthesis of polymers. To synthesize new types of molecules, the introduction of allyl may increase the activity of target organisms, and may reduce the adverse effects of their environment.

In addition, allyl bromide is indispensable for synthesis, compounds, materials, and other fields, and promotes the development of various fields.
What are the physical properties of Allyl Bromide?
Allyl bromide is an organic compound with many unique physical properties. Under normal temperature and pressure, it is a colorless to light yellow transparent liquid, which looks clear and translucent.
The smell of allyl bromide is pungent and strong, and it is uncomfortable to smell. Its boiling point is quite specific, about 70-71 ° C. At this temperature, allyl bromide gradually changes from liquid to gaseous. The melting point is relatively low, about -119 ° C. At this temperature, allyl bromide will condense into a solid state.
The density of this compound is slightly higher than that of water, about 1.40 g/mL. Difficult to dissolve in water, it is like an alienated guest in water, but it is easily soluble in many organic solvents, such as ethanol, ether, chloroform, etc., and can be fused with these organic solvents.
The vapor of allyl bromide is heavier than air and can spread to a considerable distance at a low place. In case of fire, it is easy to cause combustion and even explosion. During use and storage, special attention should be paid to fire and explosion protection. Its flash point is quite low, about -1 ° C. This property also indicates that allyl bromide is a flammable substance, and a little carelessness may cause a fire accident. In short, the physical properties of allyl bromide determine its application in chemical, pharmaceutical, and other fields. However, due to its flammability, irritation, and other characteristics, strict safety procedures must be followed when using it to prevent danger.
What is the chemistry of Allyl Bromide?
Allyl bromide (Allyl Bromide), with its active chemical properties, is a commonly used reagent in organic synthesis.
Allyl bromide has the typical properties of halogenated hydrocarbons, and its bromine atom is very active and prone to nucleophilic substitution. Because the allyl carbocation is highly stable due to the conjugation effect, the nucleophilic reagent is easy to attack the carbon atom connected to it and replace the bromine atom. For example, when reacted with sodium alcohol, an allyl ether can be formed; when reacted with sodium cyanide, a nitrile compound is obtained.
In addition, allyl bromide can also participate in the elimination reaction. Under the action of a strong base, the bromine atom is removed from the hydrogen atom on the adjacent carbon atom to form a carbon-carbon double bond to form an allyl olefin.
Because of its structure containing carbon-carbon double bonds, allyl bromide can undergo an addition reaction. Such as addition to halogens, hydrogen halides, etc., depending on the reaction conditions and reagents, double bonds can be added to introduce new functional groups.
And due to the existence of double bonds, allyl bromide can also undergo polymerization. Under the action of initiators, the intermolecular double bonds are connected to each other to form a polymer. The chemical properties of allyl bromide make it widely used in the field of organic synthesis, which can be used to prepare a variety of organic compounds and construct complex organic molecular structures.
What are the precautions for Allyl Bromide during storage and transportation?
Allyl bromide is also a chemical product. During storage and transportation, many matters need to be paid careful attention.
Bear the brunt. When storing, it must be placed in a cool and well-ventilated place. This is because it is lively and dangerous to be heated, so it is necessary to avoid heat. And it needs to be kept away from fire and heat sources. If an open flame is close, it may cause disasters and the risk of explosion must be prevented.
In addition, allyl bromide is corrosive. The storage device should be made of suitable materials, such as glass or specific plastic containers, to prevent it from reacting with the container and causing leakage. The seal must be tight to avoid volatilization, damage to its quality, and prevent harmful gases from escaping and endangering the surrounding area.
During transportation, stable transportation is the first priority. Make sure that the container is not damaged or leaked, and the road is bumpy, which is easy to cause damage to the container, so it needs to be properly fixed. Transportation vehicles should also be equipped with corresponding fire and emergency equipment, so that if something happens, they can respond in time.
In addition, allyl bromide is not low toxic, and contact can be harmful to the human body. Those who store and transport must wear protective equipment, such as gas masks, protective gloves and protective clothing, etc., and must not be negligent to ensure their own safety.
In short, the storage and transportation of allyl bromide requires caution at all times, and all precautions must be followed to ensure safety and avoid disasters.
What are the preparation methods of Allyl Bromide?
There are several ways to make allyl bromide. First, it can make allyl alcohol interact with hydrobromic acid. Allyl alcohol is placed in a suitable container and hydrobromic acid is slowly added, during which a catalyst may be required, and the temperature and reaction time are controlled. The hydroxyl group in allyl alcohol is replaced by the bromine ion in hydrobromic acid, so allyl bromide is obtained.
Second, the halogen exchange reaction is carried out with allyl chloride and sodium bromide as raw materials. Take allyl chloride and sodium bromide, dissolve them in a suitable solvent, and heat and stir them. Chlorine and bromine are exchanged between them, and the chlorine of allyl chloride is replaced by bromine, and allyl bromide is formed.
Third, the addition of propylene and hydrogen bromide in the presence of peroxides. Propylene is fed into a reactor containing hydrogen bromide and peroxide, and the reaction is stimulated by light or heat. According to the anti-Marsh rule, the hydrogen of hydrogen bromide is connected to the double-bond carbon containing more hydrogen, and the bromine is connected to the one containing less hydrogen, and the final product is allyl bromide. These various production methods have their own advantages and disadvantages, and they need to be selected according to the actual situation, such as the availability of raw materials, cost considerations, and the purity of the product.