Qiji Chemical
Products

1 Chlorotetradecane

Qiji Chemical

Specifications

HS Code

158157

Chemical Formula C4H9Cl
Molar Mass 92.568 g/mol
Appearance Colorless liquid
Odor Characteristic odor
Density 0.886 g/cm³ at 20 °C
Boiling Point 78 - 80 °C
Melting Point -123.1 °C
Solubility In Water Insoluble
Vapor Pressure 13.3 kPa at 12.9 °C
Flash Point -12 °C
Packing & Storage
Packing 100 - gram bottle of 1 - Chlorotetradecane, securely packaged for safe transport.
Storage 1 - Chlorotetradecane should be stored in a cool, well - ventilated area away from sources of ignition. Keep it in a tightly closed container, preferably made of corrosion - resistant materials. Avoid storing near oxidizing agents. Since it is flammable, ensure the storage location has proper fire - prevention measures, and is out of reach of unauthorized personnel.
Shipping 1 - Chlorotetradecane should be shipped in tightly - sealed, corrosion - resistant containers. It must comply with hazardous chemical shipping regulations, with proper labeling indicating its nature, and transported under conditions preventing leakage and exposure.
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General Information
Frequently Asked Questions
What are the physical properties of Chlorotetradecane?
1-Chlorotetradecane is an organic compound. Its physical properties are particularly important and are relevant to many fields of application.
Looking at its properties, under room temperature and pressure, 1-chlorotetradecane is a colorless to light yellow oily liquid. Its shape can be visually recognized and has a certain fluidity. This state has a deep impact on many industrial processes and laboratory operations.
Smell it, it emits a faint smell. Although it is not pungent or intolerable, it should also be paid attention when operating, because some people may feel uncomfortable with this smell.
As for the melting point, about -7 ° C. Under this low temperature state, 1-chlorotetradecane is still in a liquid state, demonstrating its low-temperature stability. When operating in a cold environment, there is no worry about freezing, which can ensure a smooth process.
The boiling point is between 290 and 292 ° C. The higher boiling point indicates that it has good stability under high temperature conditions. To gasify it, a higher temperature is required. This characteristic is widely used in chemical processes such as distillation and separation.
The density is about 0.869g/cm ³, which is lighter than water. If it is accidentally mixed with water, it will float on the water surface. This density characteristic is a key consideration in the separation and storage of the mixture. < Br >
In terms of solubility, 1-chlorotetradecane is insoluble in water, but soluble in most organic solvents, such as ethanol, ether, acetone, etc. This solubility is conducive to organic synthesis reactions, and can act as a reaction medium to promote the dissolution of reactants and improve the reaction rate and efficiency.
The physical properties of 1-chlorotetradecane are of great significance in many fields such as chemical production, organic synthesis, and materials science. It lays the foundation for its rational application and provides an important basis for related operations and research.
1-What are the chemical properties of Chlorotetradecane?
1-Chlorotetradecane, its shape is colorless to light yellow liquid. This substance has unique chemical properties and can be used one by one.
First, 1-chlorotetradecane has the general properties of halogenated alkanes. Halogen atoms (chlorine atoms) have good activity and can undergo many substitution reactions. If they meet nucleophiles, chlorine atoms are easily replaced. Take sodium alcohol as an example. Sodium alcohol has strong alkoxy nucleophilicity and can attack the carbon atoms connected to chlorine in 1-chlorotetradecane. The chlorine atoms leave to form corresponding ethers. This reaction is carried out under mild conditions and can be carried out in appropriate solvents. It is a common means of organic synthesis to prepare ether compounds.
Second, 1-chlorotetradecane can be eliminated. Under the action of strong bases, the molecules remove hydrogen chloride and form carbon-carbon double bonds. For example, in ethanol solution, when heated with potassium hydroxide, the chlorine atom and the hydrogen atom on the adjacent carbon atom are removed in the form of hydrogen chloride to form tetradecene. This reaction requires control of the reaction conditions. Factors such as temperature and concentration of bases have an impact on the reaction process and product ratio.
Third, the physical properties of 1-chlorotetradecane cannot be ignored. It is insoluble in water, has a lower density than water, and can float on the water surface. In organic solvents, such as ether and benzene, it has good solubility. This property allows it to be used in the process of organic synthesis and separation according to the principle of similar miscibility.
Fourth, 1-chlorotetradecane has certain chemical stability. It can exist stably at room temperature and pressure without special chemical environment. However, in case of high temperature, open flame or strong oxidant, there is a safety risk, or violent reactions such as combustion and explosion occur.
In short, 1-chlorotetradecane has various chemical reactivity and specific physical properties due to its halogenated alkane structure, and has important application value in organic synthesis, materials science and other fields. However, during use, it is necessary to pay attention to its chemical properties and latent risks to ensure safe operation.
What fields is Chlorotetradecane used in?
1-Chlorotetradecane is useful in many fields. In the field of material synthesis, it can be used as an intermediate. Taking the preparation of special surfactants as an example, its long-chain alkyl structure can endow surfactants with unique properties, making them effective at the interface, such as reducing surface tension, enhancing emulsification and dispersion, which is crucial in detergents, cosmetics and other industries.
In the field of organic synthesis, it is often an important raw material for the introduction of tetradecyl alkyl. Because of its suitable activity of chlorine atoms, it can react with various nucleophiles through many reactions, such as nucleophilic substitution reactions, to construct complex organic molecular structures, providing the possibility for the creation of medicinal chemistry and fine chemical products.
In the field of lubricating materials, it is also valuable. With the characteristics of long-chain alkanes, it can participate in the deployment of high-performance lubricants, enhance the strength and stability of lubricating films, reduce the friction coefficient, reduce the wear of mechanical parts, and play a role in the operation and maintenance of industrial machinery, automotive engines, etc.
In addition, in some research experiments, as a specific structural model compound, it helps scientists to deeply explore the physical and chemical properties of organic compounds and the reaction mechanism, providing experimental support for the development of related theories, and promoting the continuous progress of chemical science.
What is the production method of Chlorotetradecane?
1-Chlorotetradecane is also an organic compound. The preparation method used to follow the following methods in the past.
First, tetradecyl alcohol and chlorinated reagents are used as raw materials. Place pure tetradecyl alcohol in a suitable reaction vessel, and add an appropriate amount of catalyst, such as anhydrous zinc chloride, etc. Slowly add chlorinated reagents, such as hydrogen chloride gas, or Lucas reagent composed of concentrated hydrochloric acid and zinc chloride. During the reaction, the temperature should be carefully controlled, usually under mild heating, so that the temperature is maintained between about 50-80 ° C. The hydroxyl group of tetradecyl alcohol reacts with the chlorine atom in the chlorinated reagent, and then 1-chlorotetradecane is obtained. The reaction principle is that the hydroxyl group of the alcohol is easily replaced by the chlorine atom under the action of the catalyst to form halogenated hydrocarbons.
Second, it can be started from tetradecanoic acid. First, tetradecanoic acid and alcohols, such as ethanol, are esterified under the catalysis of concentrated sulfuric acid to obtain ethyl tetradecanoate. Later, ethyl tetradecanoate is reduced with a strong reducing agent such as lithium aluminum hydride to obtain tetradecanoic alcohol. Then according to the above method of preparing 1-chlorotetradecane from tetradecanoic alcohol, the target product can be obtained. In this process, the esterification reaction aims to convert the carboxylic acid into an ester, which is convenient for subsequent reduction. The reduction step reduces the ester group to < Br >
Or, the addition reaction is carried out with tetradecene and hydrogen chloride as raw materials. In the reaction system, an appropriate amount of peroxide is added as an initiator, and the free radical addition reaction occurs between hydrogen chloride and tetradecene under the condition of light or heating. The double bond of tetradecene is opened, and the hydrogen atom and chlorine atom of hydrogen chloride are added to the carbon atom at both ends of the double bond to generate 1-chlorotetradecane. This reaction is based on the free radical mechanism. The peroxide is thermally decomposed to produce free radicals, which initiates the addition of hydrogen chloride and tetradecene.
All preparation methods have their own advantages and disadvantages. The method of using tetradecyl alcohol as the starting material is relatively simple, but the selection of chlorination reagents and the control of reaction conditions are very critical. Although the process is a little complicated, it can provide a relatively pure intermediate product. However, the method of tetradecene preparation, the reaction conditions are relatively mild, but attention should be paid to the amount of initiator and the safety of the reaction process.
What is the market outlook for Chlorotetradecane?
1-Chlorotetradecane, as well as organic compounds, is widely used in the chemical industry. In terms of its market prospects, there are many considerable advantages.
First, in the lubricant industry, 1-Chlorotetradecane is often used as an additive. Today, industrial machinery operates at high frequencies and heavy loads, which requires strict lubricant performance. 1-Chlorotetradecane has a unique chemical structure, which can significantly improve the anti-wear and anti-friction properties of lubricants. With the advancement of industrial modernization, the demand for high-performance lubricants in machinery manufacturing, automobile manufacturing and other industries has surged, providing a broad market space for 1-Chlorotetradecane.
Second, in the field of surfactant preparation, it also plays an important role. Surfactants are indispensable in various industries such as daily chemicals, textiles, and oil extraction. 1-chlorotetradecane is a surfactant made from raw materials, which has excellent emulsifying, dispersing, and wetting properties. With the improvement of people's quality of life, the demand for daily chemical products continues to rise; the difficulty of oil extraction increases, and the demand for high-efficiency surfactants for oil displacement also rises. This has led to a steady increase in the market demand for 1-chlorotetradecane.
Furthermore, in the field of organic synthesis, 1-chlorotetradecane is a key intermediate. Chemists can convert it into various high-value-added compounds through a variety of chemical reactions. In pharmaceutical synthesis, some drug molecules need this as a starting material. With the increasing investment in pharmaceutical R & D and the increasing demand for characteristic organic intermediates, 1-chlorotetradecane, as an important member, has a bright market prospect.
However, its market development also faces challenges. Environmental protection regulations are becoming increasingly strict, and the control of pollutant emissions in the production process of 1-chlorotetradecane is tightening. Manufacturers need to invest more funds in the upgrading of environmental protection facilities to meet regulatory requirements, which may increase their production costs. And the chemical industry is fiercely competitive, and new production technologies and alternative products may pose a threat to the market share of 1-chlorotetradecane. However, overall, with its wide range of uses in many fields and irreplaceable characteristics, the future market prospect of 1-chlorotetradecane is still quite optimistic.