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Phosphorus Tribromide

Qiji Chemical

Phosphorus Tribromide
Specifications

HS Code

191401

Name Phosphorus Tribromide
Chemical Formula PBr3
Molar Mass 270.685 g/mol
Appearance Colorless to yellowish - fuming liquid
Odor Pungent, irritating odor
Density 2.852 g/cm³
Melting Point -40 °C
Boiling Point 173.2 °C
Solubility In Water Reacts violently with water
Solubility In Organic Solvents Soluble in many organic solvents like ether, carbon disulfide
Acidity Basicity Lewis acid
Oxidation State Of P +3
Vapor Pressure 1.33 kPa at 44.4 °C
Hazard Corrosive, causes severe burns to skin and eyes
Packing & Storage
Packing 1 - liter glass bottle containing Phosphorus Tribromide, securely sealed.
Storage Phosphorus tribromide should be stored in a cool, dry, well - ventilated area, away from sources of heat and ignition. It must be kept in a tightly - sealed container, preferably made of glass or a compatible plastic, to prevent contact with air and moisture. Store it separately from oxidizing agents, bases, and water - reactive substances to avoid dangerous reactions.
Shipping Phosphorus tribromide is shipped in tightly - sealed, corrosion - resistant containers. It must be transported in accordance with hazardous materials regulations, with proper labeling to indicate its corrosive and reactive nature.
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Phosphorus Tribromide Phosphorus Tribromide
General Information
Historical Development
The rise of phosphorus bromide was the beginning of the research of Western sages. In the past, various schools were dedicated to the mystery of chemistry and studied the principle of material change. The initial appearance of phosphorus bromide was the fruit of ingenious thinking and diligent experimentation by wise men.
Although the experimental method at that time was not as complete as it is today, chemists, with their perseverance and keen observation, saw its clues in the micro-phenomenon. After repeated trials, the method of preparing phosphorus bromide was obtained.
At the beginning, the yield was dilute and the quality was not pure, so this was the beginning of a new path. After years of delay, the process was gradually refined, and scholars studied the reaction conditions and the ratio of raw materials many times, resulting in the increase in the yield of phosphorus bromide and the purity of the quality.
Its use has gradually expanded, emerging in the field of organic synthesis, adding new strength to the chemical industry, and also a proof of scientific progress. From the beginning of the micro to the gradual development, it is actually the result of the wisdom and sweat of predecessors.
Product Overview
Phosphorus tribromide is an important product of chemistry. Among them, phosphorus tribromide (Phosphorus tribromide) has unique characteristics. Its shape is often a colorless to light yellow fuming liquid with a pungent smell.
Phosphorus tribromide has a wide range of uses in the chemical industry. In organic synthesis, it is often used as a brominating agent to convert alcohols into brominated hydrocarbons. This reaction is accurate and efficient, laying the foundation for the preparation of many organic compounds. And because of its lively chemistry, it is also indispensable in the pharmaceutical, fragrance and other industries.
When preparing, phosphorus and bromine need to be used as raw materials and reacted under suitable conditions. However, it is corrosive, and the procedures must be strictly followed during operation to ensure safety.
In short, phosphorus tribromide plays an important role in the chemical industry. In-depth study and good use of it will surely promote the progress of chemical technology.
Physical & Chemical Properties
Phosphorus tribromide is also a chemical substance. Its color is often light yellow, like a liquid flow, with a pungent odor. In terms of physical characteristics, its boiling point is about 178 degrees, the melting point is close to minus 40 degrees, and the density is also fixed.
In terms of its chemical properties, it is very active. In contact with water, hydrogen bromide and phosphoric acid are generated. When it meets alcohols, it also changes and forms halogenated hydrocarbons. Because of its high activity of bromine atoms, it is easy to replace with other atoms or groups.
Phosphorus tribromide is widely used in the field of organic synthesis. It is often a halogenated agent that helps to form a variety of organic halides to promote the progress of organic reactions. It is an indispensable quality in the process of chemical preparation.
Technical Specifications & Labeling
Phosphorus bromide is also a chemical material. If you want to clarify its technical specifications and labels (commodity parameters), you should consider it carefully.
Phosphorus bromide, its color or light yellow, like a liquid flow. Its nature is active, it is strong in water, and it produces acid gas of hydrogen bromide. Regarding its purity, it is often necessary to seek a high purity, and the impurities need to be small. Its boiling degree and melting degree are fixed, which is essential for identification.
When preparing, all conditions should be carefully controlled. The purity of raw materials, the temperature of reaction, and the length of time are all related to quality. The method of refining also requires wonderful skills to remove impurities and maintain its purity.
On the logo, the name, sex, and danger should be detailed. Warning words should be conspicuous to prevent accidental contact and risk. In this way, the main technical specifications and labels (product parameters) of phosphorus bromide are obtained to be used in the right way, to ensure safety and to promote business.
Preparation Method
The method of making phosphorus bromide is related to the raw material and production process, reaction steps and catalytic mechanism. Take red phosphorus as raw material and mix it with liquid bromine in an appropriate ratio. First put red phosphorus in the reactor, and then slowly inject liquid bromine. The reaction step is that the two contact at the beginning, and the phosphorus atom interacts with the bromine atom to react violently to generate phosphorus tribromide. The reaction formula is: $2P + 3Br_ {2} = 2PBr_ {3} $. This process needs to be controlled at temperature to prevent overreaction. As for the catalytic mechanism, a small amount of water or iodine can be used to catalyze to accelerate the reaction process and increase the yield. In this way, according to the raw material and process, reaction steps and catalytic mechanism, phosphorus bromide can be prepared.
Chemical Reactions & Modifications
Taste the way of chemistry, the changes are endless, and the properties of matter are all born from reactions. In today's words, the chemical reaction and modification of Phosphorus Tribromide can be quite studied.
Phosphorus Tribromide responds when it encounters water, just like the ancient war, which is very intense. It touches with water, and bromine atoms translocate with hydroxide to form hydrobromic acid and phosphoric acid, which is a common reaction.
As for modification, it can be made to meet alcohols. In suitable circumstances, the hydroxyl group of the alcohol is exchanged with the bromine of Phosphorus Tribromide to obtain halogenated hydrocarbons, which is a common technique in organic synthesis. After this modification, the properties of the substance are greatly changed, and the uses are also expanded. It can be used in the genus of pharmaceuticals and fragrances, and it is truly outstanding in the field of chemical industry.
Synonyms & Product Names
Phosphorus tribromide, its name is also known as phosphorus bromide (ⅲ). This substance is widely used in the field of chemical industry. In the process of organic synthesis, it is often a key reagent.
Although its nicknames are different, they refer to this Phosphorus Tribromide. In trade circulation, merchants may call it by different trade names according to customs and uses. Although the names are different, their essence is the same chemical substance.
In the process of industrial preparation, through specific processes and raw material compatibility, this product can be obtained. Its unique properties, in many chemical reactions, show significant activity, help the synthesis of various organic compounds, and promote the development of the chemical industry, which is of great importance to the industry.
Safety & Operational Standards
Phosphorus tribromide (Phosphorus tribromide) is a chemical commonly used in chemical research. Its preparation and use must follow strict safety and operating practices to ensure the safety of the experimenter and the smooth progress of the experiment.
Phosphorus tribromide is corrosive and has strong irritation to the skin, eyes and respiratory tract. If it is inadvertently contacted, it will burn lightly and endanger life in severe cases. Therefore, when the experimenter operates, it is necessary to wear protective clothing, protective gloves and goggles, and in a well-ventilated place to prevent inhalation of harmful gases.
In terms of operating specifications, when using phosphorus tribromide, it is necessary to use dry and clean utensils to avoid the mixing of moisture and impurities. Due to its violent reaction with water, hydrogen bromide gas and phosphoric acid are formed, which not only damages the medicine, but also causes danger. When preparing the solution, phosphorus tribromide should be slowly added to the solvent, and stirred while adding, to prevent local overheating or the reaction from getting out of control.
Storage of phosphorus tribromide should not be ignored. It should be placed in a dry, cool and ventilated place, away from fire and heat sources. At the same time, it should be stored separately from oxidizing agents and alkalis, and mixed storage should be avoided to prevent dangerous reactions. The storage place should be equipped with suitable materials to contain the leakage, so that it can be dealt with in time if an accident occurs.
If phosphorus tribromide leaks during the experiment, personnel in the leaked contaminated area should be quickly evacuated to a safe area, and quarantined to strictly restrict access Emergency responders need to wear self-contained positive pressure breathing apparatus, wear anti-acid and alkali work clothes, and do not directly contact leaks. In the case of small leaks, you can mix sand, dry lime or soda ash and collect them in a dry, clean and covered container. Large leaks need to be built embankments or dug for containment, and transferred to a tanker or special collector by pump for recycling or transportation to a waste treatment site for disposal.
In short, when using phosphorus tribromide, the experimenter must always keep in mind safety first and strictly follow the operating specifications to avoid accidents and ensure the safety and smooth operation of chemical research.
Application Area
Phosphorus tribromide is also an important chemical product. Its use is macro and wide, and it has outstanding achievements in various fields.
In the field of organic synthesis, phosphorus bromide is often a powerful reagent. It can convert alcohol compounds into halogenated hydrocarbons. This reaction is wonderful and efficient, opening up many possibilities for organic chemical synthesis paths. With its ability to change the structure and properties of compounds, it helps chemists produce a variety of new compounds.
The pharmaceutical industry also depends on its work. When synthesizing specific pharmaceutical ingredients, phosphorus bromide can promote the smooth reaction, ensuring the quality and quantity of the product. With its power, pharmaceuticals can obtain the compounds required for precision and pave the way for the creation of good medicines.
It is also indispensable for the preparation of materials. It can participate in the synthesis of material precursors, and through ingenious reactions, endow materials with unique properties, such as improving their stability and conductivity, and contribute greatly to the creation of new materials.
It can be seen that phosphoryl bromide is like a good tool in the application field, promoting the progress of chemical-related industries and helping many aspects of human life.
Research & Development
Phosphorus tribromide (Phosphorus tribromide) is an important chemical substance. I have devoted myself to my research, and have explored its properties and production methods.
It is active, interacts with water, reacts quickly, and produces hydrogen bromide and phosphoric acid. This characteristic is very useful in organic synthesis, and is often used as a brominating reagent.
The previous production method has many disadvantages that are complicated and inefficient. After months of research, I have improved the process to increase the yield and reduce the cost. The new method, using phosphorus and bromine as materials, temperature control, speed and other conditions, can obtain high-purity products.
Now phosphorus tribromide is widely used in the pharmaceutical, pesticide and fragrance industries. I will make unremitting efforts to expand its use and make every effort for the advancement of the chemical industry, hoping to promote this product to a higher level and achieve significant development.
Toxicity Research
Phosphorus tribromide is an important substance in chemical research. Its toxicity research is related to many fields.
Phosphorus tribromide is quite toxic. In experimental investigations, it can be seen that it comes into contact with the skin, can cause burns, and has a pungent smell. It enters the respiratory tract and can damage lung function. If eaten inadvertently, its poison can invade the viscera and endanger life.
However, this toxicity is not generated for no reason. The study of its chemical structure and the characteristics of its atomic combination endow it with activity, so it can react with many substances in organisms and cause toxicity.
Toxicity research, in chemical production, is related to worker safety; in environmental considerations, it is related to ecological balance. Therefore, our generation of chemical researchers should study the toxicity of Phosphorus Tribromide carefully, as the basis for protection and governance, to ensure production safety and environmental harmony.
Future Prospects
I have tried to study phosphorus bromide, and I know that it is widely used today. However, there are still many things to be expected when thinking about the future development.
Phosphorus tribromide is often a key agent in the field of chemical synthesis. However, in the future, it may be used in the preparation of emerging materials, such as nanomaterials, functional coatings, etc. With its unique chemistry, it may promote the leap in material properties, laying the foundation for various new technologies.
And in the way of pharmaceutical research and development, it is also expected to become a surprise. Or to help the synthesis of active ingredients, making the creation of new drugs more efficient and saving patients from pain. Although it has been useful today, there is still a lot of room for future expansion. With time, through unremitting research, we will be able to shine in more fields and become the key to scientific and technological progress. This is my extension of its future.
Frequently Asked Questions
What are the main uses of Phosphorus Tribromide?
Phosphorus and phosphorus tribromide have a wide range of uses. In the field of chemical industry, it is often used as a key reagent. For example, in organic synthesis, phosphorus tribromide can convert alcohols into halogenated hydrocarbons. This change is like applying a magic method to alcohols, causing their structure to change, and halogen atoms enter them to obtain new halogenated hydrocarbons.
It also has its functions in the manufacturing of medicines. It can help to form intermediates for a variety of drugs, just like building the foundation of a high-rise building, laying the foundation for the synthesis of complex and delicate drug molecules. In the reaction, it can precisely guide the construction of molecular structures, making the process of drug synthesis smoother.
Furthermore, it also plays a role in the field of materials science. Or provide assistance for the preparation of special materials, so that the materials have unique characteristics, such as specific electrical and optical characteristics. Like a stroke of genius, endow materials with different capabilities to meet various special needs.
Phosphorus and phosphorus tribromide play an important role in chemical, pharmaceutical, materials and other fields, and play an important role in promoting the progress of various industries.
What are the Physical Properties of Phosphorus Tribromide?
The physical properties of phosphorus and phosphorus tribromide, such as color, state, taste, melting boiling point, solubility and other characteristics.
Phosphorus has a variety of allotropes, common white phosphorus and red phosphorus. White phosphorus is white or light yellow in color, soft like wax, with garlic odor, and darkens in color when seen in light. White phosphorus has a low ignition point, only 40 ° C, and is prone to spontaneous combustion, so it often exists in water. Its density is 1.82g/cm ³, which is larger than water. Red phosphorus is dark red powder, odorless, with a ignition point of about 240 ° C, higher than white phosphorus, stable at room temperature, insoluble in water and carbon disulfide.
Phosphorus tribromide, the normal state is colorless or light yellow fuming liquid, with irritating odor. Its melting point is -41.5 ° C, boiling point is 173.2 ° C. It reacts violently with water to form phosphoric acid and hydrobromic acid, which are dissolved in organic solvents such as acetone and carbon disulfide. Phosphorus tribromide is highly corrosive and can corrode a variety of metals and organic matter.
The two have different physical properties and are used in chemical experiments and industrial production. White phosphorus can be used to make phosphoric acid, incendiary bombs, etc.; red phosphorus is used to make matches and pesticides. Phosphorus tribromide is often used as a chemical reagent in organic synthesis, introducing bromine atoms.
Chemical Properties of Phosphorus Tribromide
Phosphorus and phosphorus tribromide are both chemical substances with unique properties and play key roles in many chemical processes.
Phosphorus has a variety of allotropes, common ones are white phosphorus and red phosphorus. White phosphorus is white or light yellow, soft in color, highly toxic, has a very low ignition point, is easy to spontaneously ignite in air, and must be stored in water. Red phosphorus is a reddish-brown powder, which is more stable than white phosphorus, has a higher ignition point, and is non-toxic. Phosphorus is chemically active and can react with many substances. When exposed to oxygen, it can burn violently under suitable conditions, generating phosphorus pentoxide and emitting dazzling fire. This reaction is often used in military fireworks and flares.
Phosphorus tribromide is a colorless or light yellow fuming liquid with an irritating odor. Its chemical properties are also active. When hydrolyzed, it reacts violently in contact with water to form phosphoric acid and hydrogen bromide gas. This reaction is violent and accompanied by heat. Phosphorus tribromide is often used as a chemical reagent and is widely used in the field of organic synthesis. It can be used as a brominating agent to make alcohols undergo bromination reaction, and the hydroxyl group is replaced by bromine atoms to generate corresponding bromohydrocarbons, which is indispensable in the preparation of specific structural compounds in organic synthesis.
When phosphorus meets phosphorus tribromide, it can react under specific conditions. Because phosphorus has a variety of valence states, it can redox with phosphorus tribromide to generate phosphorus-containing compounds with different valence states. The specific products depend on the reaction conditions, such as temperature and the proportion of reactants. Such reactions enrich the preparation pathways of phosphorus compounds, providing more options for chemical synthesis.
What is the Preparation of Phosphorus Tribromide?
To make phosphorus tribromide, the method is as follows: First take an appropriate amount of phosphorus and place it in a corrosion-resistant device. Also prepare tribromide, the quality must be pure. Set the device in a stable place and slowly inject bromine on the phosphorus. In the meantime, it is advisable to control the temperature, so as not to cause heat to erupt suddenly and cause danger. Due to the reaction between phosphorus and bromine, the heat output is quite dramatic.
When injecting bromine, the hand should be steady and slow, and observe its corresponding state. When there is a reaction, the liquid color may change, gas or life, it is normal. When it is finished, the product may be liquid, and the color may be different.
After that, the prepared product should be purified by a suitable method. You can use the technique of distillation to choose the right temperature, remove the impurities, and make the tribromide pure. This is the method of making the tribromide of phosphorus. However, you must be careful and follow the rules to ensure safety. All utensils used should be clean and dry beforehand, to prevent impurities from entering and damaging them.
What are the precautions for using Phosphorus Tribromide?
Phosphorus and phosphorus tribromide need to be treated with caution during use.
Phosphorus is lively and prone to spontaneous combustion in the air. When taking it, it must be clipped with tweezers, and must not be touched by hand. After taking it, the remaining phosphorus must be properly stored in water to prevent accidents from contacting the air. When reacting with phosphorus tribromide, the environment must be well ventilated. Because phosphorus tribromide is easily hydrolyzed in contact with water, it releases irritating gases such as hydrogen bromide, which not only smell pungent, but also cause serious irritation and damage to the human respiratory tract and eyes. Therefore, the operation should be carried out in a fume hood to ensure that harmful gases can be discharged in time to ensure the safety of operators.
Furthermore, phosphorus tribromide is highly corrosive. During the measurement and transfer operation, protective clothing, protective gloves and goggles are required. If it is accidentally splashed on the skin or eyes, it should be rinsed with a large amount of water immediately and quickly seek medical treatment. At the same time, its reaction with phosphorus has many exothermic characteristics. Pay attention to the control of the reaction temperature during operation to prevent the reaction from getting out of control due to excessive temperature and causing danger.
In addition, the instruments used in the experiment must be kept dry and anhydrous to avoid the hydrolysis of phosphorus tribromide and affect the reaction process and results. After the reaction is completed, the remaining phosphorus tribromide and reaction products should be properly disposed of in accordance with relevant regulations and should not be discarded at will to prevent pollution and harm to the environment. Overall, it is necessary to remain vigilant during the operation and strictly follow the operating procedures to ensure the safe and smooth conduct of the experiment.